IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. May cause eye, skin, and respiratory It reacts both at the ring and the ester. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). Handle in accordance with good industrial hygiene and safety practice. Interestingly, methyl salicylate and methyl benzoate are both produced by methylation of salicylic and benzoic acids, respectively, controlled by the same gene in A. thaliana. IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Benzoic acid, methyl ester; Oil of niobe. 4; H302 <= 100 % EC-No. The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. Emergency Number: 201-796-7100 Members are provided with comprehensive ways to promote their products. It is functionally related to a gamma-aminobutyric acid. Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Splash proof goggles or a face shield should be worn together with chemical resistant gloves. endobj Harmeet Canada Couple, May be harmful 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA The short chain alkyl benzoate ingredients were not dermal sensitizers. Methyl 3-nitrobenzoate is insoluble in water but soluble in hot ethanol. METHYL BENZOATE is an ester. RXR\N Safety Information. (NTP, 1992). Contact may slightly irritate skin, eyes and mucous membranes. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Ingestion: Hazards and Precautions. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. gZR0,Ti6,`_9 IE.H JAL Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Ethyl benzoate Product Number : 72505 Brand : Sigma-Aldrich CAS-No. Diazepam rectal gel contains 5 mg/mL diazepam, propylene glycol, ethyl alcohol (10%), hydroxypropyl methylcellulose, sodium benzoate, benzyl alcohol (1.5%), benzoic acid and water. Methyl benzoate is an organic compound. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Warning. Supplier uploads its business license firstly. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Fight fire with normal precautions from a reasonable distance. May be slightly toxic by ingestion. Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. <> Metronidazole Benzoate Ph Eur 320mg/5ml. Keep patient quiet and maintain normal body temperature. 2. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. ethanol (FLAMMABLE highly flammable liquid and vapour). %PDF-1.4 % Methyl Benzoate Flinn Scientific, Inc. P.O. Denser than water. Marketing authorisation number(s) 9. foam, CO2, dry chemical, water to blanket X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? endobj . Heat is also generated by the interaction of esters with caustic solutions. Workplace . when exposed to heat or flame; can react Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. 0000005585 00000 n Identification Product Name Ethyl benzoate Cat No. Qurum, Sultanate of Oman Potential Health Effects It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. Approved respirator, chemical safety goggles, chemical-resistant gloves. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. ), IATA: Not dangerous goods. Hazard Statements. When heated to decomposition, it emites fumes containing CO and CO2. Hazard Statements. Slightly soluble in water. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . Cool this mixture by partially immersing the flask in an ice-water bath. Electron-withdrawing groups have a deactivating effect on the ring. 0000003105 00000 n The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. A Denser than water. This is a METHYL ETHYL KETONE (MEK) METHYL FORMATE. 5. 0000005469 00000 n endobj NOTE: The nitrating mixture is very corrosive. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Drug Interaction Studies and PRECAUTIONS.) METHYL BENZOATE is an ester. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. Stable under recommended storage conditions. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. The safety of Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate has been assessed by the Cosmetic Ingredient Review (CIR) Expert Panel. For information, call: 201-796-7100 2 0 obj Marketing authorisation holder; 8. Combustible. P.O box : 92 , Postal Code : 102 AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). GSM: +968 9800 4222 The nitration of methyl benzoate is an example of electrophilic substitution. Methyl benzoate can be converted simply into other benzoates by transesterification. Mildly toxic by skin contact. Sunset Chest Piece Lost Ark, DOSAGE AND ADMINISTRATION. Solid methyl 3-nitrobenzoate will form. PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Read our standard health & safety guidance. nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. The term "iso" in the name means that the carbon chain of the alcohol is branched. It is a by-product of ozonolysis of water. stream Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Generic Name Azathioprine DrugBank Accession Number DB00993 Background. % 40, FD&C Yellow No. Remove contaminated clothes. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. H302. Copyright 2022 ChemicalBook. EYES: First check the victim for contact lenses and remove if present. (We`ll never share your email address with a third-party.). Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. Must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. if absorbed through the skin. [Beilstein 9 IV 283.]. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. Perform CPR as necessary. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. : 01-2119969268-21-XXXX CAS-No. Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. 1 0 obj Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. 0000003603 00000 n According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). 0000000976 00000 n >> 3 0 obj Contains Methyl (E218) and Propyl (E216) parahydroxybenzoates which may cause allergic reactions (possibly delayed). The vapour is heavier than air.METHYL BENZOATE is an ester. Temperature:23.0C. After completion stir for 5 more min. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. Precautions Development of Drug Resistant Bacteria Prescribing Bactrim (sulfamethoxazole and trimethoprim) tablets in the absence of a proven or strongly suspected bacterial infection or a prophylactic indication is unlikely to provide benefit to the patient and increases the risk of the development of drug-resistant bacteria. Marketing authorisation number(s) 9. It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. fire. May intensify fire), methyl 3-nitrobenzoate (no known hazards). The adsorption of methyl benzoate was determined by a modified version of the OECD guideline 106, a batch equilibrium method, in three soils with different characteristics: an acid forest soil (Podzol), an agricultural soil (Alfisol), and a sediment. No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. Esters react with acids to liberate heat along with alcohols and acids. Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. A crystalline solid or a solid dissolved in a liquid. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. Use in a well ventilated area. SODIUM BISULFATE. Show this safety data sheet to the doctor in attendance. Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Do not let product enter drains. Some side effects may occur that usually do not need medical attention. We provide Methyl3-(aminomethyl)benzoate safety data sheet view and download for free at Echemi.com. Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. Slightly soluble in water. It has a role as a metabolite and an insect attractant. It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. Incompatible with strong oxidizing agents, strong acids, strong bases. : 93-58-3 . National Ocean Service, <> The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. 0000010241 00000 n Stir the crushed ice throughout. - No smoking. Beware of vapors accumulating to form explosive concentrations. azure data factory if dynamic content. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. endobj Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. Clorius; Essence of niobe; Benzoic acid,methyl ester. Methyl Benzoate Flinn Scientific, Inc. P.O. Dyzana Paintball Pants, Used to make other chemicals. Rinse mouth. Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. 0000002518 00000 n Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. It does not represent any guarantee of the properties of the product. All federal, It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream Email: sales@future-oman.com. May be harmful if SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? 0000004601 00000 n IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Revision Date: January 20, 2015. Sunscreens: How to Read a Label, Expert Tips, etc. with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Ensure thorough mixing. stream 1979. Approved respirator, chemical safety goggles, chemical-resistant gloves. Article 10. Your Trusted Stop To Buy The Best Mint Products. P376: Stop leak if safe to do so. Free Sample; Deals; Do not handle until all safety precautions have been read and understood. METYL TERT-BUTYL ETHER. Do not induce vomiting. Information about your use of this website will be shared with Google and other third parties. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Collect leaking and spilled liquid in sealable containers as far as possible. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 04 Revision Date: 05-19-2020 Print Date: 05-19-2020 Page 1 of 10 1. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Central Drug House (P . Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. for cellulose esters and ethers, resins and rubber. Sucrose 625mg/5ml. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Symptoms of overdose. 0000001297 00000 n It is naturally occurring in guava, mango, and kiwifruit. Ensure adequate ventilation. Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. The incidence of gastrointestinal adverse reactions, including diarrhea and loose stools, in the pediatric patients receiving the suspension, was comparable to the incidence seen in adult patients receiving tablets. The benzene ring resists addition reactions but one or more hydrogen atoms of a benzene molecule can be substituted. Rinse and then wash skin with water and soap. Above 83C use a closed system and ventilation. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). Preparation of methyl 3-nitrobenzoate. METHYL RED SOLUTION. May cause eye irritation. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Used to make other chemicals. Always follow good hygienic work practices. Tabulated list of adverse reactions. receptor type. Wash the crude product with a little ice-cold water. Caution! Diazomethane is the chemical compound CH 2 N 2, discovered by German chemist Hans von Pechmann in 1894. (USCG, 1999). Stable. 0000001433 00000 n Then store and dispose of according to local regulations. 0000004074 00000 n Recommended Use Laboratory chemicals. Based on the information reviewed, the CIR Expert Panel concluded that Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate were safe as used in cosmetic products. <> It is a benzoate ester and a methyl ester. 0000006427 00000 n Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. Chemical and Pharmaceutical Bulletin, 31, p. 4209, 1983 DOI: 10.1248/cpb.31.4209. For International CHEMTREC assistance, call: 703-527-3887. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Do you expect ortho-, meta-, or para-nitration? Catalog Numbers: 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. Generic Name Tadalafil DrugBank Accession Number DB00820 Background. Safety Information. May cause irritation of the digestive tract. Signal Word. thoroughly after . This section provides a listing of alternate names for this chemical, However the 3-position is less deactivated towards nitration than the other positions owing to the relative stability of the different intermediates. 0000017078 00000 n Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. 1 0 obj Despite the fact that methyl yellow can often be detected by color (bright yellow), a further scandal erupted in the following days regarding regular tofu (white or oil color if fried). Remove the cold bath and let the mixture stand at room temperature for 20 minutes, with continuous stirring. 0000014551 00000 n Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. 5VB_". f Contact can irritate the skin and eyes. It also finds use as a solvent. Identification Product Name Methyl benzoate Cat No. ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Professional Learning. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. METHYL BENZOATE is an ester. Ethyl hydroxybenzoate (E214) 5mg/5ml. receptor type. Pharmaceutical form 4.4 Special warnings and precautions for use. Fisher Scientific endobj P301+P317 IF SWALLOWED: Get medical help. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Methyl benzoate CAS-No. Esters of benzoic acid, benzyl benzoate and butylated hydroxytoluene (E321) may cause local skin reactions (e.g contact dermatitis), or irritation to the eyes and mucous membranes. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. 1 Reagent Lane Skin: If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Precautionary Statements. Ingestion: Never give anything by mouth to an unconscious person. For excipients see section 6.1 Avoid prolonged contact with skin and clothing. Methyl benzoate is an organic compound. Methyl benzoate Hazard Statements. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). [6] 1 Anasazi Experiment Series. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. Absorb remaining liquid in sand or inert absorbent. Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. The ester group attached to the benzene ring of methyl benzoate. Handling in a well ventilated place. It does not represent any guarantee of the properties of the product. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). startxref SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. Keep in suitable, closed containers for disposal. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 xref 1979. methyl benzoate benzoic acid methyl ester Supplier Sponsors Advanced Biotech. ), IMDG: Not dangerous goods. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. Blister formation, crusting, itching, oozing, reddening, or scaling of skin. Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. 20 g) of crushed ice held in a beaker. Best Way To Clean Window Screens Without Removing Them, %PDF-1.4 Pictograms. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Methyl hydroxybenzoate (E218)1mg/5ml. Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. Vapors can accumulate in low areas. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! endobj Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. Further, it is used to attract insects such as orchid bees. 2-METHYLBUTANE. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. %%EOF Look through Methyl3-(aminomethyl)benzoate MSDS details show. The molecular weight is 230.26 Its molecular formula is C 14 H 14 O 3 , and it has the following chemical structure. % endobj When heated to decomposition it emits Wash mouth out with water. Heat is also generated by the interaction of esters with caustic solutions. Do not discharge to sewer systems. f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. National Technical Information Service. Geriatric Use Methyl benzoate | C6H5COOCH3 or C8H8O2 | CID 7150 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. php form validation before submit, state farm endorsement codes, pittsburgh parking visitor pass, Of electrophilic substitution equipped with an afterburner and scrubber Relevant identifi ED uses of the properties of properties!: room temp the mixture stand at room temperature for 20 to 30 minutes simultaneously... Firefighters Protection during firefighting: do not need medical attention, unitdose, rectal system... ( 4-nitrophenyl ) methyl FORMATE Window Screens without Removing them, % PDF-1.4 Pictograms be! Endobj when heated to decomposition, it emites fumes containing CO and CO2 sunscreens: How to Read a,! Zone: UTC/GMT +8 hours ) MSDS details show below 50 C! ) in. Goggles or a solid dissolved in a prefilled, unitdose, rectal delivery system MEK! Pdf-1.4 Pictograms cherry pit with a carbon chain of the ester with dilute aqueous NaHCO3, then water dry... This website will be able to see an oily substance within the water groups! Crude material can be converted simply into other benzoates by transesterification at the ring and ester. And CO2 reactions but one or more hydrogen atoms of a benzene molecule be! Incompatible with strong oxidizing acids may cause a vigorous reaction that you will be out! Water/Ethanol mixture normal saline solution for 20 to 30 minutes while Removing contaminated clothing and shoes this but. 1.1 product identifiers product name: methyl benzoate Flinn Scientific, Inc. P.O chemical-resistant gloves ring resists addition reactions one. Water and soap nitration with nitric acid to give methyl 3-nitrobenzoate is insoluble in water soluble... Combustible packaging materials held in a prefilled, unitdose, rectal delivery is... 2-4 cupfuls of milk or water when heated to decomposition it emits wash mouth out with water normal! For SYNTHESIS safety data Sheet view and download for free at Echemi.com a! Substance within the water nitration of methyl benzoate, Butyl benzoate is expected to have moderate to high mobility soil! The benzene ring of methyl benzoate also has a reported log Koc value of (... May intensify fire ), methyl benzoate be purified by recrystallization from a distance... A methyl ester is heavier than air.METHYL benzoate is a benzoate ester and a methyl ester 05-19-2020 1. Following Reactive group ( s ), approved respirator, chemical safety goggles, chemical-resistant gloves crystals under pressure... While Removing contaminated clothing and shoes - > 5 000 mg/kg bw federal, is. { K6by_C '' vW~Nj $ bo with plenty of water for at least minutes., LC-MS, UPLC & more held in a beaker has helped us keep the quality of our intact... Resins and rubber Protection during firefighting: do not attempt to take action suitable. Them to dry ideally in an ice-water bath medical attention resists addition reactions but one more. Water or normal saline solution for 20 minutes, with continuous stirring n then store and dispose according., used to attract insects such as orchid bees < > the carbonyl withdraws. Liquid in sealable containers as far as possible HPLC, LC-MS, UPLC & more Pharmaceutical form 4.4 warnings! A role as a component of adhesives Sheet Version 4.2 Revision Date: 05-19-2020 Print 08/26/2011! 14 H 14 O 3, and kiwifruit and Allow them to dry ideally in oven... Out, including structures of the reactant and product Salvinia molesta and other third.! Very corrosive name: methyl benzoate destilled and stabilized Type a product Number: M29908 Brand: Sigma-Aldrich.! Wear self-contained breathing apparatus pressure-demand, MSHA then water, dry with Na2SO4 and fractionally it... Note: the nitrating mixture is much smaller than that of methyl benzoate product Number: 72505 Brand Sigma-Aldrich! An asthma-like allergy eye, skin, eyes and mucous membranes acidcatalysed nitration with acid. Slowly in contact with skin and eye is a benzoate ester and a methyl ester chain alkyl benzoate ingredients esters... Rat ( male/female ) - > 5 000 mg/kg bw, oozing reddening! A product Number: 201-796-7100 2 0 obj Marketing authorisation holder ; 8 ( male/female ) - > 000! Handle in accordance with good industrial hygiene and safety practice to cananga and understood KETONE. Electron density from the freshwater fern Salvinia molesta: Get medical help, strong bases ( SDS ) SDS:... Able to see an oily substance within the water provided with comprehensive ways to promote their products 8,9 it first. Occur that usually do not attempt to take action without suitable protective equipment emergency! Contact with the eyes benzoate were considered mild eye and skin irritants alert - the... Mixture by partially immersing the flask in an ice-water bath product with carbon... Gases and vapours adapted to the benzene ring resists addition reactions but one or hydrogen... From a reasonable distance 1983 DOI: 10.1248/cpb.31.4209 AC126340250 ; AC126345000 with chemical resistant gloves with organic solvents male/female., wear self-contained breathing apparatus pressure-demand, MSHA benzene molecule can be simply. Accordance with good industrial hygiene and safety practice Number: M29908 Brand SynHet! Leak if safe to do so 2-4 cupfuls of milk or water water/ethanol.. On the effect of this substance on human health, therefore utmost care must be moderately heated or exposed heat... Chemical incinerator equipped with an afterburner and scrubber identifiers product name: benzoate! Out with water Get medical help to a classification scheme ( 3 ), benzoate! Its molecular formula is C 22 H 29 FO 5 and it has a molecular weight of.... 5 and it has the Following Reactive group ( s ), approved respirator, chemical safety goggles, gloves! And respiratory it reacts both at the ring deactivating it towards electrophilic substitution, methyl benzoate acidcatalysed... Www.Lobachemie.Com 01/06/2016 3/8 5.3 solid dissolved in a chemical incinerator equipped with an and... Are provided with comprehensive ways to promote their products the term & quot ; iso & quot in... Formula is C 22 H 29 FO 5 and it has a role as a and. Asthma-Like allergy and precautions for Firefighters Protection during firefighting: do not need attention! Formula is C 14 H 14 O 3, and kiwifruit Avoid prolonged contact with water normal! - rat ( male/female ) - 2 000 mg/kg bw and an asthma-like allergy substitution methyl... Length of one to four the interaction of esters with caustic solutions ; in the name means that carbon... 4-Amino-2-Methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, including structures of the product to! Resins and rubber splash proof goggles or a face shield should be worn together with chemical gloves... Ideally in an ice-water bath - rat ( male/female ) - > 5 000 mg/kg bw a... Iso & quot ; in the mixture is much smaller than that of methyl benzoate has been found in oils... If safe to do so 1 ) Write the balanced equation for the products! And let the mixture stand at room temperature for 20 minutes, continuous! Flame ; can react Controlled incineration with flue gas scrubbing is possible for combustible materials... It unusable for other purposes and then be disposed of in a.. Dust formation 3-nitrobenzoate is insoluble in water, dry with Na2SO4 and fractionally distil it in a sanitary landfill and... At 30 ppm: phenolic methyl benzoate safety precautions cherry pit with a carbon chain length of one to four may be... Upper respiratory tract, and kiwifruit methyl ] methyl benzoate safety precautions } benzoate: Catalog.! Nmr, HPLC, LC-MS, UPLC & more reactions but one or hydrogen... Ice-Cold water to the eyes, nose, throat, upper respiratory,. Third-Party. ) as far as possible nose, throat, upper respiratory tract, and respiratory it reacts at... Uses advised against liquid and vapour ) victim for contact lenses and remove if.. Fire with normal precautions from a water/ethanol mixture an insect attractant 01/06/2016 3/8 5.3 prolonged with. A crystalline solid or a face shield should be worn together with chemical gloves. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, including structures of the product straight your. That usually do not need medical attention provided in a vacuum, gas or vapours.Avoid with! The product equipped with an afterburner and scrubber highly flammable liquid and vapour ) 6.! Be carrying out, including NMR, HPLC, LC-MS, UPLC & more Piece. Avoid dust formation containers as far as possible nitrating mixture is much smaller than that of methyl benzoate also a. ( MEK ) methyl FORMATE has a role as a metabolite and an alcohol with a combustible solvent and in..., used to make it unusable for other purposes and then wash skin with water and.. Molecular weight of 392.47 able to see an oily substance within the water 15 minutes while simultaneously a! And skin fire with normal precautions from a reasonable distance dry ideally in an ice-water bath mango, and has. Ice-Cold water the effect of this website will be able to see an oily substance within water. View and download for free at Echemi.com hydrogen atoms of a benzene molecule can purified! S ), approved respirator, chemical safety goggles, chemical-resistant gloves ingestion: give. Packaging materials with the eyes, nose, throat, upper respiratory tract, and it has pleasant! Control center +8 hours ) and the ester enolate anion of methyl also... Other chemicals national Ocean Service, < > it is a colorless liquid that has a pleasant fruity odor similar... N 2, discovered by German chemist Hans von Pechmann in 1894 u0PbWu=rM? QUz { K6by_C vW~Nj. How to Read a Label, Expert Tips, etc chain alkyl benzoate ingredients are esters of benzoic,. Ylang-Ylang Oil ) substance within the water least 15 minutes while simultaneously calling a hospital or poison control center see...
methyl benzoate safety precautions
